Spectroscopic and Computational Studies of Perfluorophenyl and Perfluoro-2-naphthyl Nitrenes in Shpolskii Matrixes

Autor:	Bolesław Kozankiewicz, I. Deperasinska, Z. Zhu, H. B. Zhai, C. M. Hadad
Rok vydání:	1999
Předmět:	Solvent chemistry.chemical_compound chemistry Nitrene Aryl Photodissociation Azide Hydrogen atom Physical and Theoretical Chemistry Photochemistry Fluorescence Spectral line
Zdroj:	Scopus-Elsevier
ISSN:	1520-5215 1089-5639
DOI:	10.1021/jp9902304
Popis:	Fluorescence and fluorescence excitation spectra of the photolysis products of perfluorophenyl azide and perfluoro-2-naphthyl azide in n-hexane and n-heptane at 5 K were recorded. The spectra with (0,0) transitions at 18 800 and 18 300 cm-1 were assigned to perfluorophenyl nitrene and perfluoro-2-naphthyl nitrene, respectively. A narrow spectrum with a (0,0) transition at 17 300 cm-1 was attributed to the aryl aminyl radical derived from perfluoro-2-naphthyl nitrene formed by abstraction of a hydrogen atom from the surrounding solvent matrix. The experimental results are consistent with calculations using semiempirical, B3LYP, and CASSCF/CASPT2 methods.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::694ab06d77d2c1333fb4092e9b64cd0a https://doi.org/10.1021/jp9902304 Zobrazit plný text záznamu