How Metal Ion Lewis Acidity and Steric Properties Influence the Barrier to Dioxygen Binding, Peroxo O-O Bond Cleavage, and Reactivity

Autor:	Julian A. Rees, Stefan Stoll, Guang Yang, Xianru Sun, Marc C. Piquette, Maksym A. Dedushko, Ellen C. Hayes, Julie A. Kovacs, Audra Johansen, Elena V. Rybak-Akimova, Santiago Toledo, Penny Chaau Yan Poon
Rok vydání:	2019
Předmět:	inorganic chemicals Steric effects Chemistry Kinetics General Chemistry 010402 general chemistry 01 natural sciences Biochemistry Catalysis 0104 chemical sciences Metal Colloid and Surface Chemistry visual_art Polymer chemistry visual_art.visual_art_medium Reactivity (chemistry) Bond cleavage
Zdroj:	Journal of the American Chemical Society. 141(38)
ISSN:	1520-5126
Popis:	Herein we quantitatively investigate how metal ion Lewis acidity and steric properties influence the kinetics and thermodynamics of dioxygen binding versus release from structurally analogous Mn–O2...
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::68cdf405b05bf128b8f786307964c346 https://pubmed.ncbi.nlm.nih.gov/31480847 Zobrazit plný text záznamu