A new type of alumoxane obtained by controlled hydrolysis of N,N-dialkylcarbamato complexes of aluminium: crystal and molecular structure of [Al4(µ3-O)2 (O2CNPri2)8]
| Autor: | Stefan Kaskel, Daniela Belli Dell'Amico, Luca Labella, Ulrich Abram, Riccardo Rovai, Fabio Marchetti, Fausto Calderazzo, Joachim Strähle |
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| Jazyk: | angličtina |
| Rok vydání: | 1997 |
| Předmět: |
Metals and Alloys
chemistry.chemical_element General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Crystal chemistry.chemical_compound Crystallography Hydrolysis chemistry Aluminium Materials Chemistry Ceramics and Composites Molecule Derivative (chemistry) Stoichiometry |
| Popis: | The aluminium(III) N,N-diisopropylcarbamato derivative [Al2(O2CNPri2)6] undergoes hydrolysis with a stoichiometric amount of water giving the µ3-oxo derivative [Al4(µ3-O)2(O2CNPri2)8], which is analytically, spectroscopically and structurally characterized. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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