Controllable Layered Structures in Polyoxomolybdate-Surfactant Hybrid Crystals
| Autor: | Toshihiro Yamase, Takeru Ito |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2010 |
| Předmět: |
Materials science
Chemical substance surfactant Inorganic chemistry Stacking Crystal structure lcsh:Technology Article Pulmonary surfactant Monolayer polyoxometalate Molecule General Materials Science lcsh:Microscopy lcsh:QC120-168.85 lcsh:QH201-278.5 lcsh:T inorganic-organic hybrid crystal Chemical engineering lcsh:TA1-2040 Polyoxometalate lcsh:Descriptive and experimental mechanics lcsh:Electrical engineering. Electronics. Nuclear engineering Science technology and society lcsh:Engineering (General). Civil engineering (General) lcsh:TK1-9971 |
| Zdroj: | Materials, Vol 3, Iss 1, Pp 158-164 (2010) Materials Volume 3 Issue 1 Pages 158-164 |
| ISSN: | 1996-1944 |
| Popis: | Inorganic-organic hybrid crystals containing α-octamolybdate (Mo8) or hexamolybdate (Mo6) were isolated by using hexadecyltrimethylammonium (C16) surfactant. The packing mode of the inorganic layers depended on a difference in the polyoxomolybdate molecular structure. The structure for both crystals consisted of alternate stacking of C16 organic bilayers and polyoxomolybdate inorganic layers with a periodicity of 24.4–24.6 Å. However, the C16-Mo8 crystals contained Mo8 monolayers, while the C16-Mo6 crystals contained Mo6 bilayers. These lattice structures for the polyoxometalate/organic hybrid will be designed by the molecular structures of polyoxometalate. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|