Samarium(II)-induced ring-expansion reaction of 1,2-cyclobutanedicarboxylates to produce cyclopentanones

Autor: Ikuo Shinohara, Hiroto Nagaoka
Rok vydání: 2004
Předmět:
Zdroj: Tetrahedron Letters. 45:1495-1498
ISSN: 0040-4039
Popis: Novel ring-expansion reaction of 1,2-cyclobutanedicarboxylates with Sm(II) in the presence of HMPA with a catalytic amount of methanol was found to provide 2-oxocyclopentanecarboxylates.
Databáze: OpenAIRE