Coordinating properties of the anionic ligand (MeCO)2C(−)C(X)Me (X=O or NH) toward transition metal(II) centers
| Autor: | Marino Basato, Elisabetta Caneva, Augusto C. Veronese, Cristina Tubaro |
|---|---|
| Rok vydání: | 2009 |
| Předmět: |
3-Acetylpentane-2
Transition metal complexes Metal acetates beta-Imino diketonato complexes N O coordination 4-dionato complexes Ethanol Ligand Inorganic chemistry Medicinal chemistry Inorganic Chemistry chemistry.chemical_compound chemistry Transition metal Nucleophile Materials Chemistry ACPD Physical and Theoretical Chemistry Sodium carbonate |
| Zdroj: | Inorganica Chimica Acta. 362:2551-2555 |
| ISSN: | 0020-1693 |
| DOI: | 10.1016/j.ica.2008.11.017 |
| Popis: | The exchange reaction between transition metal(II) acetates and the protic nucleophiles 3-(1-aminoethylidene)pentane-2,4-dione ( Hampd ) or 3-acetylpentane-2,4-dione ( Hacpd ) affords the corresponding [M( ampd ) 2 ] (M = Ni ( 1 ), Pd ( 2 )) or [M( acpd ) 2 ] (M = Mn ( 5 ), Fe ( 6 ), Ni ( 7 ), Cu ( 8 ), Pd ( 9 )) complexes in fair to good yields. The reaction is performed in ethanol at room temperature, with addition of sodium carbonate in some cases. This last new synthetic procedure is applied for those complexes which easily undergo an extensive deacylation process. The factors determining the success of the exchange reaction and the resulting N,O or O,O coordination are fully discussed. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect