Temperature switchable Brønsted acid-promoted selective syntheses of spiro-indolenines and quinolines
| Autor: | Erik V. Van der Eycken, Pavel Fedoseev |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
Indole test
010405 organic chemistry Chemistry Quinoline Metals and Alloys General Chemistry 010402 general chemistry 01 natural sciences Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound Materials Chemistry Ceramics and Composites Organic chemistry Brønsted–Lowry acid–base theory |
| Zdroj: | Chemical communications (Cambridge, England). 53(55) |
| ISSN: | 1364-548X |
| Popis: | A high-yielding, temperature switchable divergent approach towards the synthesis of either spiro-indolenines or quinolines is described, starting from easily available indolyl ynones. The application of TFA at rt promotes the dearomatization of the indole, resulting in the formation of the spiro-indolenine, while at higher temperature, rearrangement results in the formation of the quinoline. crosscheck: This document is CrossCheck deposited related_data: Supplementary Information identifier: Erik Van der Eycken (ORCID) copyright_licence: The Royal Society of Chemistry has an exclusive publication licence for this journal history: Received 4 April 2017; Accepted 26 April 2017; Accepted Manuscript published 26 April 2017; Advance Article published 11 May 2017; Version of Record published 6 July 2017 ispartof: Chemical Communications vol:53 issue:55 pages:7732-7735 ispartof: location:England status: published |
| Databáze: | OpenAIRE |
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