catena-Poly[[dichloridocobalt(II)]-μ-4,4′-bis(benzimidazol-1-yl)biphenyl]

Autor:	Chenzhong Yao, Zhuangwei Wei, Hui Li, Qiuping Han, Qiaojuan Gong
Rok vydání:	2011
Předmět:	Metal-Organic Papers Biphenyl Benzimidazole Ligand Bridging ligand General Chemistry Dihedral angle Condensed Matter Physics Bioinformatics Ring (chemistry) Chloride chemistry.chemical_compound Crystallography chemistry medicine General Materials Science Benzene medicine.drug
Zdroj:	Acta Crystallographica Section E: Structure Reports
ISSN:	1600-5368
DOI:	10.1107/s1600536811010671
Popis:	In the title compound, [CoCl(2)(C(26)H(18)N(4))](n), the Co(II) atom (site symmetry 2) is tetra-hedrally coordinated by two chloride ions and two N atoms from 4,4'-bis-(benzimidazol-1-yl)biphenyl ligands: the complete ligand is generated by crystallographic twofold symmetry. The dihedral angle between the benzene rings is 34.67 (8)° and the angle between the benene ring and the adjacent benzimidazole ring system is 43.26 (10)°. The bridging ligand links the Co(II) atoms into chains propagating in [[Formula: see text]01].
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::67ed7fa866ce98c89fc0fae9eeec845c https://doi.org/10.1107/s1600536811010671 Zobrazit plný text záznamu