Hydrogen activation with perfluorinated organoboranes: 1,2,3-tris(pentafluorophenyl)-4,5,6,7-tetrafluoro-1-boraindene
| Autor: | Heikki M. Tuononen, Virve A. Karttunen, Warren E. Piers, Adrian Y. Houghton |
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| Rok vydání: | 2014 |
| Předmět: |
Tris
Hydrogen Chemistry Metals and Alloys Cyclohexene Crystallographic data chemistry.chemical_element General Chemistry Photochemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound Polymer chemistry Materials Chemistry Ceramics and Composites ta116 Antiaromaticity |
| Zdroj: | Chem. Commun.. 50:1295-1298 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/c3cc48796b |
| Popis: | The perfluorinated boraindene was synthesized and fully characterized. Both computational and crystallographic data show that is antiaromatic. Compound was shown to react reversibly with H2 and to catalyse the hydrogenation of cyclohexene. The mechanism of catalysis was probed experimentally and computationally. |
| Databáze: | OpenAIRE |
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