1D and 3D coordination polymers based on the Cu 3 ( μ 3 -OH)( μ -pz) 3 and Cu(Hpz) 3 SBUs connected by the flexible glutarate dianion
| Autor: | Corrado Di Nicola, C. Pettinari, Massimo Gazzano, Magda Monari, Luciano Pandolfo, Arianna Lanza, Enrico Forlin, Fabrizio Nestola |
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| Přispěvatelé: | Forlin, Enrico, Lanza, Arianna, Di Nicola, Corrado, Monari, Magda, Gazzano, Massimo, Nestola, Fabrizio, Pettinari, Claudio, Pandolfo, Luciano |
| Jazyk: | angličtina |
| Rok vydání: | 2018 |
| Předmět: |
chemistry.chemical_classification
Chemistry Inorganic chemistry Trinuclear derivatives 02 engineering and technology Polymer 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Inorganic Chemistry Solvent Coordination polymers Bicarboxylate Crystallography Copper(II) Void space Pyrazole Materials Chemistry Coordination polymer SBus Physical and Theoretical Chemistry 0210 nano-technology Porosity Bicarboxylates |
| Zdroj: | Inorganica Chimica Acta (Testo stamp.) 470 (2018): 385–392. doi:10.1016/j.ica.2017.09.004 info:cnr-pdr/source/autori:Forlin, Enrico; Lanza, Arianna; Di Nicola, Corrado; Monari, Magda; Gazzano, Massimo; Nestola, Fabrizio; Pettinari, Claudio; Pandolfo, Luciano/titolo:1D and 3D coordination polymers based on the Cu3<%2Finf>(?3<%2Finf>-OH)(?-pz)3<%2Finf> and Cu(Hpz)3<%2Finf> SBUs connected by the flexible glutarate dianion/doi:10.1016%2Fj.ica.2017.09.004/rivista:Inorganica Chimica Acta (Testo stamp.)/anno:2018/pagina_da:385/pagina_a:392/intervallo_pagine:385–392/volume:470 |
| Popis: | [object Object]Different synthetic procedures lead to different coordination polymers (CPs) based either on the trinuclear triangular [Cu3(? 3-OH)(?-pz)3]2+ or on the mononuclear [Cu(Hpz)3]2+ (Hpz=pyrazole) secondary building units (SBUs), bridged by the flexible glutarate (Glu) dianion. The mononuclear complex [Cu(HGlu)2(Hpz)4] was also obtained as byproduct. One of the CPs based on the trinuclear SBU displays a relevant porosity due to three intersecting channels, accounting for about 40% of the solvent accessible void space. |
| Databáze: | OpenAIRE |
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