Synthesis and coordination behaviour of aluminate-based quinolyl ligands
| Autor: | Schirin Hanf, Marina Rincón-Nocito, Jessica E. Waters, Raúl García-Rodríguez, Dominic S. Wright, Andrew D. Bond, Annie L. Colebatch |
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| Přispěvatelé: | Hanf, Schirin [0000-0003-2624-7872], Bond, Andrew D [0000-0002-1744-0489], García-Rodríguez, Raul [0000-0003-0699-3894], Wright, Dominic S [0000-0002-9952-3877], Colebatch, Annie L [0000-0001-6920-3744], Apollo - University of Cambridge Repository |
| Rok vydání: | 2021 |
| Předmět: |
Materials science
34 Chemical Sciences 010405 organic chemistry Aluminate chemistry.chemical_element Type (model theory) 010402 general chemistry 01 natural sciences 0104 chemical sciences 3. Good health Inorganic Chemistry Metal 3402 Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry visual_art visual_art.visual_art_medium Lithium |
| Popis: | The effects of moving the donor N-atom from the 2-position in lithium (2-pyridyl)- and (2-quinolyl)aluminates to the more remote position in (8-quinolyl)aluminates have been investigated by solid-state structural and DFT computational studies of the new complexes [{EtAl(2-qy)3}Li(μ-X)Li(THF)3] (X = Cl/Br 62 : 38) [(1)Li(μ-X)Li(THF)3], [{(EtAl(2-qy)3)Li}2(μ-Br)]−Li(THF)4+ [{1Li}2(μ-Br)]−Li(THF)4+, [{EtAl(2-Me-8-qy)3}Li] [(2)Li], [{Me2Al(2-Me-8-qy)2}Li(THF)] [(3a)Li(THF)], [{Me2Al(6-Me-2-py)2}Li(THF)2] [(4)Li(THF)2] and [{{EtAl(2-Me-8-qy)2}2O}(Li2THF)] (5). Increasing the remoteness of the donor N-atom from the bridgehead results in large differences in the coordination of the Li+ cations by the (8-quinolyl)aluminate anions compared to 2-quinolyl or 2-pyridyl counterparts. The results are of potential interest in understanding how the coordination sites of ligands of this type can be tuned for the coordination requirements of specific metal centres. |
| Databáze: | OpenAIRE |
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