Electroorganic reactions. Part 58. Revisiting the cleavage of oxalate ester radical-anions

Autor:	James H. P. Utley, Shalini Ramesh
Jazyk:	angličtina
Rok vydání:	2003
Předmět:	lcsh:QD241-441 chemistry.chemical_compound chemistry lcsh:Organic chemistry Radical Organic Chemistry Substituent Organic chemistry Cyclic voltammetry Cleavage (embryo) Medicinal chemistry Oxalate
Zdroj:	ARKIVOC, Vol 2003, Iss 12, Pp 18-26 (2003)
ISSN:	1551-7012 1551-7004
Popis:	Electrochemically-generated radical-anions of oxalate esters undergo cleavage. For those of ethyl 4-substituted benzyl oxalates the rates of cleavage have been measured by cyclic voltammetry combined with digital simulation. Consideration of substituent effects and earlier product studies presents compelling evidence for an EC mechanism with the cleavage resulting in oxalate anions and benzyl radicals.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::673c758d1d2c2401aedaf2db3da00426 https://www.arkat-usa.org/arkivoc-journal/browse-arkivoc/ark.5550190.0004.c03 Zobrazit plný text záznamu