First observation of the B̃A11 state of SiH2 and SiD2 radicals by optical-optical double resonance spectroscopy

Autor:	Yasuhiko Muramoto, Naohiko Mikami, Haruki Ishikawa
Rok vydání:	2005
Předmět:	Chemistry Analytical chemistry General Physics and Astronomy Level structure Resonance Linearity Bending State (functional analysis) Physical and Theoretical Chemistry Atomic physics Quantum number Spectroscopy Spectral line
Zdroj:	The Journal of Chemical Physics. 122:154302
ISSN:	1089-7690 0021-9606
DOI:	10.1063/1.1881172
Popis:	The B1A1 state of SiH2 and SiD2 was observed by the optical-optical double resonance technique for the first time. The electronic band origin of the B state of SiD2 was determined to be 27 214.11 cm(-1). A very clear exclusive behavior depending on the even/odd value of the bending vibrational quantum number was observed in the spectra, representing a quasilinear behavior of the B state. The barrier height to linearity was estimated to be approximately 125 cm(-1) by the quasilinear analysis of the bending vibrational level structure of SiD2.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6734e650fb3f1fc1d91a73743277942e https://doi.org/10.1063/1.1881172 Zobrazit plný text záznamu