Synthesis of Perfluorinated Isoquinolinediones through Visible-Light-Induced Cyclization of Alkenes

Autor:	Jie Li, Zhu-Ping Xiao, Wen-Xin Wang, Ruilong Sheng, Ying-Chun Wang, You-Lin Deng, Shi Tang, Guo-Liang Ding, Ming-Wei Wang
Rok vydání:	2015
Předmět:	Reaction conditions Chemistry Organic Chemistry Combinatorial chemistry Visible spectrum
Zdroj:	The Journal of Organic Chemistry. 80:12599-12605
ISSN:	1520-6904 0022-3263
Popis:	A novel visible-light-induced carboperfluoroalkylation of alkenes using perfluoroalkyl iodides and bromides as Rf sources, leading to isoquinoline-1,3-diones, was developed. This method offers rapid entry to perfluorinated isoquinoline-1,3(2H,4H)-diones from N-alkyl-N-methacryloyl benzamides under mild reaction conditions, allowing for the incorporation of a wide variety of perfluorinated groups such as CF3, C3F7, C4F9, C6F13, C8F17, C10F21, and CF2CO2Et.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::67341989b0d2a7e359c14d79cd5ad608 https://doi.org/10.1021/acs.joc.5b01803 Zobrazit plný text záznamu