Irreversible Resistive State Switching in Devices with a Homoleptic Cobalt(II) Complex Active Layer

Autor: Biswajit K. Barman, Manas Khatua, Bappaditya Goswami, Ratheesh K. Vijayaraghavan, Subhas Samanta
Rok vydání: 2021
Předmět:
Zdroj: Chemistry – An Asian Journal. 16:1545-1552
ISSN: 1861-471X
1861-4728
DOI: 10.1002/asia.202100152
Popis: Molecules with bi-stable electronic transport behaviour have been in upfront research topics of the molecular semiconductor devices in the past few decades due to the use of such materials in resistive data storage devices. Transition metal complexes (TMC) are expected to be potential candidates in regard to the tunable and manifold redox behaviour expecting multiple bulk transport states. Finding alternate mechanisms in such devices with TMC as the active layer materials would revoke the multifaceted approach to the functional gain. We have succeeded in demonstrating write once-read many (WORM) type of resistive memory device using a homoleptic Cobalt(II) (Co(II)) complex with large on/off current ratio ensuring the easy readout process at lower voltage. The advantage of this device was the turn on voltage was found to be the low (
Databáze: OpenAIRE
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