When Molecular Magnetism Meets Supramolecular Chemistry: Multifunctional and Multiresponsive Dicopper(II) Metallacyclophanes as Proof-of-Concept for Single-Molecule Spintronics and Quantum Computing Technologies?
| Autor: | Danielle Cangussu, Salah-Eddine Stiriba, Yves Journaux, Cynthia L. M. Pereira, Nicolás Moliner, Juan Faus, Renato Rabelo, Joan Cano, Rafael Ruiz-García, Miguel Julve |
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| Přispěvatelé: | Instituto de Ciencia Molecular (ICMol), Universitat de València (UV), Universidade Federal de Goiás [Goiânia] (UFG), Universidade Federal de Minas Gerais [Belo Horizonte] (UFMG), Institut Parisien de Chimie Moléculaire (IPCM), Chimie Moléculaire de Paris Centre (FR 2769), Institut de Chimie du CNRS (INC)-École normale supérieure - Paris (ENS Paris), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Centre National de la Recherche Scientifique (CNRS)-Ecole Nationale Supérieure de Chimie de Paris - Chimie ParisTech-PSL (ENSCP), Université Paris sciences et lettres (PSL)-Ecole Superieure de Physique et de Chimie Industrielles de la Ville de Paris (ESPCI Paris), Université Paris sciences et lettres (PSL)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut de Chimie du CNRS (INC)-École normale supérieure - Paris (ENS Paris), Université Paris sciences et lettres (PSL)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS) |
| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: |
ligand design
molecular spintronics Magnetism molecular magnetism Supramolecular chemistry Nanotechnology 010402 general chemistry 01 natural sciences quantum computing lcsh:Chemistry electron exchange Materials Chemistry Molecule [CHIM.COOR]Chemical Sciences/Coordination chemistry copper complexes electron transport Spin (physics) Quantum Quantum computer nanotechnology Spintronics 010405 organic chemistry business.industry metallosupramolecular chemistry 0104 chemical sciences Electronic Optical and Magnetic Materials metallacyclic complexes lcsh:QD1-999 Chemistry (miscellaneous) Photonics business |
| Zdroj: | Magnetochemistry, Vol 6, Iss 69, p 69 (2020) Magnetochemistry Magnetochemistry, MDPI, 2020, 6 (4), pp.69. ⟨10.3390/magnetochemistry6040069⟩ |
| ISSN: | 2312-7481 |
| DOI: | 10.3390/magnetochemistry6040069⟩ |
| Popis: | International audience; Molecular magnetism has made a long journey, from the fundamental studies on through-ligand electron exchange magnetic interactions in dinuclear metal complexes with extended organic bridges to the more recent exploration of their electron spin transport and quantum coherence properties. Such a field has witnessed a renaissance of dinuclear metallacyclic systems as new experimental and theoretical models for single-molecule spintronics and quantum computing, due to the intercrossing between molecular magnetism and metallosupramolecular chemistry. The present review reports a state-of-the-art overview as well as future perspectives on the use of oxamato-based dicopper(II) metallacyclophanes as promising candidates to make multifunctional and multiresponsive, single-molecule magnetic (nano)devices for the physical implementation of quantum information processing (QIP). They incorporate molecular magnetic couplers, transformers, and wires, controlling and facilitating the spin communication, as well as molecular magnetic rectifiers, transistors, and switches, exhibiting a bistable (ON/OFF) spin behavior under external stimuli (chemical, electronic, or photonic). Special focus is placed on the extensive research work done by Professor Francesc Lloret, an outstanding chemist, excellent teacher, best friend, and colleague, in recognition of his invaluable contributions to molecular magnetism on the occasion of his 65th birthday. |
| Databáze: | OpenAIRE |
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