Total synthesis of broussonetine F: the orthoamide Overman rearrangement of an allylic diol
| Autor: | Shohei Miwa, Takaaki Sato, Noritaka Chida, Miki Yamazaki, Naoto Hama, Toshihiro Aoki |
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| Rok vydání: | 2011 |
| Předmět: |
Allylic rearrangement
Pyrrolidines Molecular Structure Chemistry Stereochemistry organic chemicals Organic Chemistry Diol Total synthesis Alcohol Stereoisomerism Biochemistry Catalysis Overman rearrangement chemistry.chemical_compound Alkaloids Broussonetia Broussonetine F Physical and Theoretical Chemistry Tartrates |
| Zdroj: | Organic letters. 13(4) |
| ISSN: | 1523-7052 |
| Popis: | A first total synthesis of broussonetine F from diethyl l-tartrate was achieved. The cornerstone of our synthesis was an orthoamide Overman rearrangement, which provided an allylic amino alcohol with complete diastereoselectivity. |
| Databáze: | OpenAIRE |
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