On the formation chemistry of brominated polycyclic aromatic hydrocarbons (BrPAHs)

Autor:	Ibrahem S. Altarawneh, Mohammednoor Altarawneh
Rok vydání:	2021
Předmět:	Environmental Engineering Halogenation Health Toxicology and Mutagenesis Public Health Environmental and Occupational Health Environmental Chemistry General Medicine General Chemistry Polycyclic Aromatic Hydrocarbons Bromine Pollution
Zdroj:	Chemosphere. 290
ISSN:	1879-1298
Popis:	Brominated polycyclic aromatic hydrocarbons (BrPAHs) have been consistently detected in various environmental matrices, and measured at alarming rates in stack emissions. However, formation mechanisms and bromination patterns of BrPAHs remain unclear. This contribution constructs detailed mechanistic pathways for the synthesis of selected BrPAHs (namely bromine-bearing naphthalene, acenaphthylene, anthracene, and phenanthrene). Mapped-out pathways follow the Bittner-Howard's route in the hydrogen abstraction acetylene addition (HACA) mechanism, in which a second C
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::66b01f96a094582f9ba7a0916cd5ba9c https://pubmed.ncbi.nlm.nih.gov/34933028 Zobrazit plný text záznamu Full Text from ScienceDirect