Rhodium(iii )-catalyzed C–C coupling of 7-azaindoles with vinyl acetates and allyl acetates
| Autor: | Cheng-Qi Wang, Xiao-Mei Zhang, Lin Dong, Hui Lin, Shuai-Shuai Li |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
010405 organic chemistry
Chemistry Organic Chemistry chemistry.chemical_element 010402 general chemistry 01 natural sciences Biochemistry Medicinal chemistry Coupling reaction 0104 chemical sciences Catalysis Rhodium C c coupling Organic chemistry Physical and Theoretical Chemistry Selectivity Carbonylation |
| Zdroj: | Organic & Biomolecular Chemistry. 14:229-237 |
| ISSN: | 1477-0539 1477-0520 |
| DOI: | 10.1039/c5ob02096d |
| Popis: | The behaviour of electron-rich alkenes with 7-azaindoles in rhodium(III)-catalyzed C-H activation is investigated. Various substituted vinyl acetates and allyl acetates as coupling partners reacted smoothly providing a wide variety of 7-azaindole derivatives, and the selectivity of the coupling reaction is alkene-dependent. In addition, the approaches of rhodium(III)-catalyzed dehydrogenative Heck-type reaction (DHR) and carbonylation reaction were quite novel and simple. |
| Databáze: | OpenAIRE |
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