1,3-Dipolar Cycloaddition of Ethyl Diazoacetate to Alkynes in the Pores of Zeolite NaY

Autor: Yoichi Masui, Keijiro Kobayashi, Yuta Igura, Makoto Onaka, Shouhei Imachi
Rok vydání: 2007
Předmět:
Zdroj: Chemistry Letters. 36:60-61
ISSN: 1348-0715
0366-7022
DOI: 10.1246/cl.2007.60
Popis: Zeolite NaY promotes 1,3-dipolar cycloaddition of ethyl diazoacetate to alkynes having an electron-withdrawing group to afford the corresponding functionalized pyrazoles in high yields. The activation of the dipolarophile inside the pores of NaY is proposed based on the 13 C MAS NMR analysis.
Databáze: OpenAIRE