Expression of supramolecular chirality in aggregates of chiral amide-containing surfactants
| Autor: | Nico A. J. M. Sommerdijk, Ama Pistorius, Pjja Buynsters, Martinus C. Feiters, Binne Zwanenburg, Rjm Roeland Nolte, D. G. Geurts, H. Akdemir |
|---|---|
| Přispěvatelé: | Macromolecular and Organic Chemistry |
| Jazyk: | angličtina |
| Rok vydání: | 1998 |
| Předmět: |
Supramolecular chirality
Stereochemistry Hydrogen bond aggregations Metal ions in aqueous solution Organic Chemistry Supramolecular chemistry chirality General Chemistry Catalysis supramolecular chemistry surfactants chemistry.chemical_compound Crystallography chemistry helical structures Amide hydrogen bonds Molecule Imidazole Chirality (chemistry) |
| Zdroj: | Chemistry : a European Journal, 4, 1, pp. 127-136 Chemistry : A European Journal, 4(1), 127-136. Wiley-VCH Verlag Chemistry : a European Journal, 4, 127-136. Wiley-v c h verlag gmbh |
| ISSN: | 0947-6539 |
| Popis: | We can induce or altersupramolecular expressionof chirality in the aggregates of a series of chiral amide-containing surfactants (1, R = C(O)C3H7, C6H5; R′ = C11H23, C17H35; X = phosphate, imidazole) by changing the pH or by addition of metal ions. Chirality at a higher level, such as in the formation of helical structures, is found to depend strongly on the head-group organisation of the surfactant molecules. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Plný text