Concentration-dependent ion correlations impact the electrochemical behavior of calcium battery electrolytes

Autor:	Nathan T. Hahn, Julian Self, Darren M. Driscoll, Naveen Dandu, Kee Sung Han, Vijayakumar Murugesan, Karl T. Mueller, Larry A. Curtiss, Mahalingam Balasubramanian, Kristin A. Persson, Kevin R. Zavadil
Rok vydání:	2022
Předmět:	General Physics and Astronomy Physical and Theoretical Chemistry
Zdroj:	Physical Chemistry Chemical Physics. 24:674-686
ISSN:	1463-9084 1463-9076
Popis:	Ion interactions strongly determine the solvation environments of multivalent electrolytes even at concentrations below that required for practical battery-based energy storage. This statement is particularly true of electrolytes utilizing ethereal solvents due to their low dielectric constants. These solvents are among the most commonly used for multivalent batteries based on reactive metals (Mg, Ca) due to their reductive stability. Recent developments in multivalent electrolyte design have produced a variety of new salts for Mg
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::665ffda21f15fffe8fb957e69c97f23a https://doi.org/10.1039/d1cp04370f Zobrazit plný text záznamu