The First Organocatalytic Cope Rearrangement

Autor:	Christoph Schneider, Konrad Gebauer
Rok vydání:	2016
Předmět:	010405 organic chemistry Chemistry Iminium General Chemistry Sigmatropic reaction 010402 general chemistry Photochemistry 01 natural sciences Combinatorial chemistry Catalysis 0104 chemical sciences Organocatalysis Catalytic efficiency Cope rearrangement
Zdroj:	Angewandte Chemie (International ed. in English). 55(46)
ISSN:	1521-3773
Popis:	Exploiting the concept of iminium ion catalysis led to the discovery of the first organocatalytic Cope rearrangement of 1,5-hexadiene-2-carboxaldehydes. A diazepane catalyst exhibited optimal catalytic efficiency and offers possibilities for chiral modification.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::66521a05cc168c1c932b69c88df2fad3 https://pubmed.ncbi.nlm.nih.gov/27717104 Zobrazit plný text záznamu Plný text