Bimetallic Nickel Complexes Supported by a Planar Macrocyclic Diphosphoranide Ligand

Autor:	Andie R. Delaney, Li‐Juan Yu, Vincent Doan, Michelle L. Coote, Annie L. Colebatch
Rok vydání:	2023
Předmět:	Organic Chemistry General Chemistry Catalysis
Zdroj:	Chemistry – A European Journal. 29
ISSN:	1521-3765 0947-6539
DOI:	10.1002/chem.202203940
Popis:	Metal-metal cooperativity is emerging as an important strategy in catalysis. This requires appropriate ligand scaffolds that can support two metals in close proximity. Here we report nickel-promoted formation of a dinucleating planar macrocyclic ligand that can support bimetallic dinickel(II) and dinickel(I) complexes. Reaction outcomes can be tuned by variation of the substituents and reaction conditions to favour dinucleating macrocyclic, mononucleating macrocyclic or conventional pincer architectures.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::65f996ed4f7cbfcbed985b30149fd3c4 https://doi.org/10.1002/chem.202203940 Zobrazit plný text záznamu Plný text