1,3-Dioxopyrrolo[3,4-b]porphyrins: Synthesis and Chemistry
| Autor: | Carla M. B. Carvalho, Filipe A. Almeida Paz, Artur M. S. Silva, José A. S. Cavaleiro, Maria G. P. M. S. Neves, Augusto C. Tomé |
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| Rok vydání: | 2010 |
| Předmět: |
Models
Molecular Porphyrins Molecular Structure Absorption spectroscopy Organic Chemistry Biochemistry Porphyrin Medicinal chemistry Cycloaddition chemistry.chemical_compound X-Ray Diffraction chemistry Yield (chemistry) Pyrroles Physical and Theoretical Chemistry Oxygen Compounds Imide Derivative (chemistry) |
| Zdroj: | Organic Letters. 13:130-133 |
| ISSN: | 1523-7052 1523-7060 |
| DOI: | 10.1021/ol102691s |
| Popis: | A novel 1,3-dioxopyrrolo[3,4-b]porphyrin (2) has been synthesized in 70% yield following a [4 + 2] cycloaddition reaction of pyrrolo[3,4-b]porphyrin 1 with (1)O(2). The new imide was used as a template to other 1,3-dioxopyrrolo[3,4-b]porphyrins and to the corresponding open counterparts. The UV/vis absorption spectra of the new compounds show significant red-shifts when compared with those of the nonsubstituted analogues. The structure of an imide derivative was confirmed by single-crystal X-ray diffraction. |
| Databáze: | OpenAIRE |
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