Convergent approach to complex spirocyclic pyrans: practical synthesis of the oxa-pinnaic acid core

Autor:	Andrew James Ledgard, Adele E. Pasqua, Frank D. Ferrari, Rodolfo Marquez
Rok vydání:	2013
Předmět:	Alkaloids Pinnaic acid Molecular Structure Chemistry Stereochemistry Organic Chemistry Enantioselective synthesis Spiro Compounds Physical and Theoretical Chemistry Biochemistry Tertiary alcohols Asymmetric induction Pyrans
Zdroj:	Organicbiomolecular chemistry. 11(21)
ISSN:	1477-0539
Popis:	The enantioselective synthesis of the oxa-pinnaic acid framework has been achieved through internal asymmetric induction. The synthetic strategy pursued illustrates the adaptability of the Achmatowicz oxidative rearrangement for the synthesis of complex spirocyclic pyrans starting from tertiary alcohols.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::65b05d84cc07f1c0d2a4b2a0749fcb0a https://pubmed.ncbi.nlm.nih.gov/23589153 Zobrazit plný text záznamu