2,2-Bis(phenylselanyl)-1-(p-tolyl)vinyl 2-Oxo-2-(p-tolyl)acetate
| Autor: | Vu Thai Hung, Akihiro Nomoto, Yuki Yamamoto, Akiya Ogawa, Motohiro Sonoda, Shintaro Kodama, Kei Mihara, Tomokazu Saeki |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2021 |
| Předmět: |
chemistry.chemical_classification
benzoyl peroxide Addition reaction Geminal Alkene addition reaction Organic Chemistry Alkyne Benzoyl peroxide Biochemistry Medicinal chemistry Diselenide chemistry.chemical_compound chemistry medicine alkyne oxidation reaction Physical and Theoretical Chemistry Benzene Diphenyl diselenide diselenide Inorganic chemistry medicine.drug QD146-197 |
| Zdroj: | Molbank, Vol 2021, Iss M1283, p M1283 (2021) |
| ISSN: | 1422-8599 |
| Popis: | 2,2-Bis(phenylselanyl)-1-(p-tolyl)vinyl 2-oxo-2-(p-tolyl)acetate was synthesized via the reaction of p-tolylacetylene with diphenyl diselenide and benzoyl peroxide in benzene under atmospheric conditions. The molecular structure of the synthesized compound was evaluated using single-crystal X-ray analysis and spectral analyses. The process reported here provides a rare example of the direct and selective transformation of a terminal alkyne to the corresponding geminal diseleno-substituted alkene. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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