Solvent-free thiophene-based electrolytes: synthesis of new liquid-crystalline ionic conductors for batteries: part I
| Autor: | Damian Pociecha, Ida Chojnacka, Michal Filapek, Monika Marzec, Agnieszka Iwan, Paweł Gancarz, Krzysztof Artur Bogdanowicz |
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| Rok vydání: | 2018 |
| Předmět: |
Battery (electricity)
Materials science Inorganic chemistry Ionic bonding 02 engineering and technology Electrolyte Carbon-13 NMR 010402 general chemistry 021001 nanoscience & nanotechnology Electrochemistry 01 natural sciences 0104 chemical sciences Inorganic Chemistry chemistry.chemical_compound chemistry Thiophene Thermal stability 0210 nano-technology Electrochemical window |
| Zdroj: | Dalton transactions (Cambridge, England : 2003). 47(44) |
| ISSN: | 1477-9234 |
| Popis: | New liquid crystalline thiophene esters, thiophene-3-yl 3,4,5-tris(n-dodecan-1-yloxy)benzoate (ThBz1) and thiophene-3-yl 3,4,5-tris[4-(n-dodecan-1-yloxy)benzyloxy]benzoate (ThBz2), were synthesized for use in lithium-ion batteries as safe, new solvent-free ionic conductors. Both compounds were synthesized in multi-step reactions and were characterized via1H, 13C NMR and FT-IR spectroscopy, confirming the formation of the desired products. ThBz1 and ThBz2 showed good thermal stability and liquid crystalline behaviour. Electrochemical tests demonstrated a wide electrochemical window of 4 V for both tested ThBz compounds. Moreover, preliminary battery tests for new electrolytes in the LiCoO2/Li4Ti5O12 system confirmed their applicability in lithium-ion batteries. |
| Databáze: | OpenAIRE |
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