| Autor: |
Jianxing Xia, Yi Zhang, Marco Cavazzini, Simonetta Orlandi, Bin Ding, Hiroyuki Kanda, Nadja Klipfel, Xiao‐Xin Gao, Qurat Ul Ain, Vygintas Jankauskas, Kasparas Rakstys, Ruiyuan Hu, Zeliang Qiu, Abdullah M. Asiri, Hobeom Kim, Paul J. Dyson, Gianluca Pozzi, Mohammad Khaja Nazeeruddin |
| Rok vydání: |
2022 |
| Předmět: |
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| Zdroj: |
Angewandte Chemie (International ed. in English). 61(48) |
| ISSN: |
1521-3773 |
| Popis: |
Hole-transporting materials (HTMs) based on the 10H, 10'H-9,9'-spirobi [acridine] core (BSA50 and BSA51) were synthesized, and their electronic properties were explored. Experimental and theoretical studies show that the presence of rigid 3,6-dimethoxy-9H-carbazole moieties in BSA 50 brings about improved hole mobility and higher work function compared to bis(4-methoxyphenyl)amine units in BSA51, which increase interfacial hole transportation from perovskite to HTM. As a result, perovskite solar cells (PSCs) based on BSA50 boost power conversion efficiency (PCE) to 22.65 %, and a PSC module using BSA50 HTM exhibits a PCE of 21.35 % (6.5×7 cm) with a V |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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