Rare earth element uptake mechanisms in plankton in the Estuary and Gulf of St. Lawrence

Autor: Duc Huy, Dang, Wei, Wang, Gesche, Winkler, Anique, Chatzis
Rok vydání: 2023
Předmět:
Zdroj: Science of The Total Environment. 860:160394
ISSN: 0048-9697
DOI: 10.1016/j.scitotenv.2022.160394
Popis: The global shift toward green energy alternatives escalates demands for new resources, including rare earth elements (REEs), as per their implications in various green innovations. However, our understanding of their environmental cycle, especially the interactions with aquatic organisms, remains deficient, ultimately hindering environmental protection efforts. Here, we investigate the accumulation of REEs and 18 other elements in bulk and sorted plankton collected with different net mesh sizes (30, 63, 200, 333, 500 μm) in the Estuary and Gulf of St. Lawrence in the summer and winter of 2020. We observed significant correlations between the concentrations of REEs and elements of different charge numbers and ionic radii (Ba, Co, Cs, Fe, Mn, Pb, Rb and V), indicating non-selective uptake of REEs into plankton. All these elements have their highest concentrations in the fluvial corridor and upper estuary, with more significant enrichment in phytoplankton ([La] = 26.4 ± 4.8 mg kg
Databáze: OpenAIRE