Synthesis and characterization of ruthenium(II) complexes of 2′-hydroxychalcones
| Autor: | Georges Tarrago, Claude Marzin, José A. S. Cavaleiro, Artur M. S. Silva |
|---|---|
| Přispěvatelé: | UFPA, Center of Genomics and System Biology, Institut Européen des membranes (IEM), Centre National de la Recherche Scientifique (CNRS)-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Université Montpellier 2 - Sciences et Techniques (UM2)-Institut de Chimie du CNRS (INC)-Université de Montpellier (UM) |
| Jazyk: | angličtina |
| Rok vydání: | 1999 |
| Předmět: |
chemistry.chemical_classification
integumentary system 010405 organic chemistry Chemistry Dimethyl sulfoxide Stereochemistry Ligand organic chemicals Potassium chemistry.chemical_element Salt (chemistry) General Chemistry 010402 general chemistry Mass spectrometry 01 natural sciences Medicinal chemistry Catalysis 0104 chemical sciences Ruthenium chemistry.chemical_compound Materials Chemistry [CHIM]Chemical Sciences Two-dimensional nuclear magnetic resonance spectroscopy ComputingMilieux_MISCELLANEOUS |
| Zdroj: | New Journal of Chemistry New Journal of Chemistry, Royal Society of Chemistry, 1999, 23 (3), pp.329-336. ⟨10.1039/a809005j⟩ |
| ISSN: | 1144-0546 1369-9261 |
| Popis: | Reaction of cis-RuCl2(DMSO)4 with the potassium salts of 2′-hydroxychalcones L leads to the stable complexes RuL2(DMSO)2. For each ligand L three isomers of each bis(dimethyl sulfoxide)bis(chalconato)ruthenium(II) complex were found; in two of them the two chalconates and the two DMSO ligands are equivalent, while in the third one the chalconates and DMSO ligands are inequivalent. Only two isomers of the RuL2(DMSO)2 complex were obtained by the reaction of cis-RuCl2(DMSO)4 with the potassium salt of the 2′-hydroxy-3,4,4′,5,6′-pentamethoxydihydrochalcone. One of these isomers was also obtained by the reduction of the appropriate bis(dimethyl sulfoxide)bis(chalconato)ruthenium(II) complex. All these complexes were fully characterized by extensive NMR studies, mass spectrometry and elemental analysis. The unequivocal stereochemistry of each RuL2(DMSO)2 complex was established by NOESY experiments. |
| Databáze: | OpenAIRE |
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