Conversion of D-Fructose into Ethyl Lactate Over a Supported SnO2–ZnO/Al2O3 Catalyst
| Autor: | Nataliia L. Hes, Svitlana V. Prudius, Volodymyr Brei |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2019 |
| Předmět: |
Ethanol
010405 organic chemistry SnO2/Al2O3 catalyst Fructose Raw material equipment and supplies 010402 general chemistry 01 natural sciences ethyl lactate 0104 chemical sciences Catalysis Autoclave fructose lcsh:Chemistry chemistry.chemical_compound Colloid and Surface Chemistry chemistry lcsh:QD1-999 Chemistry (miscellaneous) Yield (chemistry) Ethyl lactate Selectivity Nuclear chemistry |
| Zdroj: | Colloids and Interfaces, Vol 3, Iss 1, p 16 (2019) Colloids and Interfaces Volume 3 Issue 1 |
| ISSN: | 2504-5377 |
| Popis: | The study is directed to the search of a simple effective catalyst for ethyl lactate obtained from fructose as renewable raw material. A series of SnO2-containing oxides prepared by impregnation of alumina were characterized by several techniques in order to determine their textural and acid-base properties. The transformation of a 13% fructose solution in 98% ethanol over SnO2/Al2O3 catalysts using autoclave rotated with 60 rpm at 160 ° C for 3 h was studied. It was found that doping SnO2/Al2O3 samples with ZnO improves selectivity towards ethyl lactate. The supported SnO2-ZnO/Al2O3 catalyst provides 100% fructose conversion with 55% yield of ethyl lactate at 160 ° C. A possible scheme of fructose transformation into ethyl lactate on L-acid IVSn4+ sites is discussed. |
| Databáze: | OpenAIRE |
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