Supramolecular architecture in crystalline Bu2NH2(PhPO3H)2SnMe3

Autor:	Libasse Diop, Djibril Fall, Jeferson Gomes Da Silva, Tidiane Diop
Jazyk:	angličtina
Rok vydání:	2012
Předmět:	hydrogenophosphonate Chemistry Metals and Alloys Supramolecular chemistry Nanotechnology General Chemistry snme3-containing framework Condensed Matter Physics trigonal bipyramidal environment x-ray Materials Chemistry Architecture infinite chain structure QD1-999
Zdroj:	Main Group Metal Chemistry, Vol 35, Iss 1-2, Pp 63-65 (2012)
ISSN:	2191-0219 0792-1241
Popis:	The title compound Bu2NH2(PhPO3H)2SnMe3 was synthesized and its structure determined by single crystal X-ray crystallography. The structure consists of two monodentate hydrogenophosphonates [PhPO3H]- bonded to SnMe3 groups leading to SnC3O2 moiety in a trans trigonal bipyramidal environment. [(PhPO3H)2SnMe3]- dimerizes through hydrogen bonds. Dibutylammonium (Bu2NH2+) cations are hydrogen bonded to the dimeric moieties through phosphonates to give a chain structure.
Databáze:	OpenAIRE
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