Synergistic Dual Transition Metal Catalysis

Autor:	Sang‐gi Lee, Da Jung Jung, U. Bin Kim, Hyun Ji Jeon, Kris Rathwell
Rok vydání:	2020
Předmět:	Transition metal Chemistry Synergistic catalysis General Chemistry Combinatorial chemistry Dual (category theory) Catalysis
Zdroj:	Chemical Reviews. 120:13382-13433
ISSN:	1520-6890 0009-2665
DOI:	10.1021/acs.chemrev.0c00245
Popis:	Synergistic catalysis, a type of plural catalysis which utilizes at least two different catalysts to enable a reaction between two separately activated substrates, has unlocked a plethora of previously unattainable transformations and novel chemical reactivity. Despite the appreciable utility of synergistic catalysis, specific examples involving two transition metals have been limited, as ensuring a judicious choice of reaction parameters to prevent deactivation of catalysts, undesirable monocatalytic event(s) leading to side products, or premature termination and other potentially troublesome outcomes present a formidable challenge. Excluding those driven by photocatalytic mechanisms, this review will highlight the reported examples of reactions that make use of two simultaneous catalytic cycles driven by two transition metal catalysts.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::64c3a5c81bbb43d855dc59f9bcc9ae46 https://doi.org/10.1021/acs.chemrev.0c00245 Zobrazit plný text záznamu