| Autor: |
Jiangyou, Long, Yan, Li, Ziqing, Ouyang, Mingjie, Xi, Junwei, Wu, Jinghao, Lin, Xiaozhu, Xie |
| Rok vydání: |
2022 |
| Předmět: |
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| Zdroj: |
Journal of Colloid and Interface Science. 628:534-544 |
| ISSN: |
0021-9797 |
| DOI: |
10.1016/j.jcis.2022.08.039 |
| Popis: |
Micro/nano-textured metal or metal oxide surfaces that are naturally superhydrophilic will spontaneously transform into hydrophobic even superhydrophobic after being exposed to ambient air due to the adsorption of airborne organics. This fast wettability transition not only affects the true evaluation of surface wettability but also deteriorates the application performance. Albeit the mechanisms responsible for the wettability transition have been clarified, there is no universal method to recover the initial superhydrophilicity, and how the surface morphology affects the wettability transition is still unclear. Herein, we observe and compare the wettability transition of a wide variety of micro/nano-textured metal or metal oxide surfaces and propose a solvent cleaning method to recover their original superhydrophilicity. We prove that the spontaneously adsorbed organics can be removed by our proposed cleaning method while maintaining the original surface morphology and composition. Our proposed cleaning method is valid for both micro/nano-textured metal and metal oxide surfaces. We also prove that the rate of the wettability transition is not primarily affected by the specific area of surface structures but by the closeness of structural arrangement. Densely packed surface nanostructures can significantly delay the wettability transition by suppressing the diffusion of organic molecules. Our results help the true evaluation of surface wettability and provide a route for the design and preparation of long-lasting superhydrophilic surfaces. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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Full Text from ScienceDirect