Synthesis of lithium corrole and its use as a reagent for the preparation of cyclopentadienyl zirconium and titanium corrole complexes

Autor:	Mariusz Tasior, Beata Koszarna, Daniel T. Gryko, John Arnold, Heather L. Buckley, Wayne A. Chomitz
Rok vydání:	2012
Předmět:	Models Molecular Porphyrins Inorganic chemistry chemistry.chemical_element Lithium Catalysis chemistry.chemical_compound Deprotonation Cyclopentadienyl complex Polymer chemistry Materials Chemistry Organometallic Compounds Corrole Group 2 organometallic chemistry Titanium Zirconium Lithium amide Molecular Structure Metals and Alloys General Chemistry Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry Reagent Ceramics and Composites
Zdroj:	Chemical communications (Cambridge, England). 48(87)
ISSN:	1364-548X
Popis:	The lithium corrole complex (Mes(2)(p-OMePh)corrole)Li(3)·6THF (1·6THF), prepared via deprotonation of the free-base corrole with lithium amide, acts as precursor for the preparation of cyclopentadienyl zirconium(iv) corrole (2) and pentamethylcyclopentadienyl titanium(IV) corrole (3).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6455f62e286eef29396ee66532b33ebb https://pubmed.ncbi.nlm.nih.gov/23014670 Zobrazit plný text záznamu