Separation and Determination of Fe(III) and Fe(II) in Natural and Waste Waters Using Silica Gel Sequentially Modified with Polyhexamethylene Guanidine and Tiron
| Autor: | Olga Zaporogets, S. L. Didukh, Vladimir N. Losev, Elena V. Borodina, A. K. Trofimchuk, Nikolay Maksimov |
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| Rok vydání: | 2017 |
| Předmět: |
Detection limit
Tiron lcsh:QD71-142 Sorbent Article Subject Chemistry Silica gel General Chemical Engineering 010401 analytical chemistry Inorganic chemistry lcsh:Analytical chemistry Sorption 02 engineering and technology 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Computer Science Applications Analytical Chemistry chemistry.chemical_compound Adsorption Polyhexamethylene guanidine Diffuse reflection 0210 nano-technology Instrumentation Research Article |
| Zdroj: | Journal of Analytical Methods in Chemistry, Vol 2017 (2017) Journal of Analytical Methods in Chemistry |
| ISSN: | 2090-8873 2090-8865 |
| DOI: | 10.1155/2017/8208146 |
| Popis: | Silica gel, sequentially modified with polyhexamethylene guanidine and pyrocatechin-3,5-disulfonic acid (Tiron), was suggested for sorption separation and determination of Fe(III) and Fe(II). It was found that quantitative extraction of Fe(III) and its separation from Fe(II) were attained at pH 2.5–4.0, while quantitative extraction of Fe(II) was observed at pH 6.0–7.5. An intensive signal with g=4.27, which is characteristic for Fe(III), appeared in EPR spectra of the sorbents after Fe(II) and Fe(III) sorption. During interaction between Fe(II) and Tiron, fixed on the sorbent surface, its oxidation up to Fe(III) occurred. Red-lilac complexes of the composition FeL3 were formed on the sorbent surface during sorption regardless of initial oxidation level of iron. Diffuse reflectance spectrum of surface complexes exhibited wide band with slightly expressed maxima at 480 and 510 nm. Procedures for separation and photometric determination of Fe(III) and Fe(II) at the joint presence and total Fe content determination as Fe(II) in waste and natural waters was developed. The limit of detection for iron was 0.05 μg per 0.100 g of the sorbent. The calibration graph was linear up to 20.0 μg of Fe per 0.100 g of the sorbent. The RSD in the determination of more than 0.2 μg of Fe was less than 0.06. |
| Databáze: | OpenAIRE |
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