Tailoring the properties of manganocene: formation of magnetic superalkali/superhalogen
| Autor: | Ricardo Inostroza-Rivera, Arindam Chakraborty, G. Naaresh Reddy, Santanab Giri, Rakesh Parida |
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| Rok vydání: | 2019 |
| Předmět: |
Manganocene
010304 chemical physics Hydrogen Organic Chemistry chemistry.chemical_element 010402 general chemistry 01 natural sciences Catalysis 0104 chemical sciences Computer Science Applications Inorganic Chemistry chemistry.chemical_compound Nonlinear optical Crystallography Computational Theory and Mathematics chemistry Cyclopentadienyl complex 0103 physical sciences Molecule Moiety Physical and Theoretical Chemistry |
| Zdroj: | Journal of molecular modeling. 25(8) |
| ISSN: | 0948-5023 |
| Popis: | A new magnetic superalkali/superhalogen molecule based on the sandwich complex manganocene is reported. The hydrogen atoms of the cyclopentadienyl rings are periodically substituted with electron-donating and electron-withdrawing ligands (or both) to design substituted manganocene complexes. The substituted manganocene complexes exhibit the properties of superalkali and/or superhalogen depending on the nature of the substituents. The substituents, therefore, act as "switches" that can modify the properties of the parent manganocene moiety by keeping its magnetic nature intact. The substituted complexes also show marked nonlinear optical behavior. |
| Databáze: | OpenAIRE |
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