Synthesis and structural characterisation of transition metal fluoride sulfates
| Autor: | Qianlong Wang, Mark T. Weller, Kayleigh L. Marshall, Hannah S. I. Sullivan |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
Diffraction
Materials science 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Bioinformatics 01 natural sciences 0104 chemical sciences Inorganic Chemistry chemistry.chemical_compound Crystallography Transition metal chemistry 0210 nano-technology Structural motif Single crystal Fluoride |
| Zdroj: | Dalton Transactions. 45:8854-8861 |
| ISSN: | 1477-9234 1477-9226 |
| DOI: | 10.1039/c6dt00582a |
| Popis: | Eleven first row transition metal fluoride sulfates synthesised in hydrofluorothermal conditions have been structurally characterised by single crystal X-ray diffraction and exhibit a wide variety of structural motifs. The polyionic structures containing Ti, V, Mn and Fe vary from discrete polyhedral units in Na4TiF4(SO4)2 and [N2C10H12] TiF4SO4, through one dimensional chains in (K2FeF3SO4, Li3FeF2(SO4)2·H2O, Li1.87Ti1.13O0.39F1.61(SO4)2, [N2C10H12]TiF2(SO4)2, [N2C6H16]Fe(SO4)2F and [N2C6H16]V(SO4)2F), and to two dimensional layers in ([N2C6H16](2+)Mn2F2(SO4)2, Na2VF3SO4 and Na3CrF2(SO4)2). |
| Databáze: | OpenAIRE |
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