High-Voltage and Intrinsically Safe Sodium Metal Batteries Enabled by Nonflammable Fluorinated Phosphate Electrolytes

Autor:	Hui Li, Hui Chen, Xiaohui Shen, Xingwei Liu, Yongjin Fang, Faping Zhong, Xinping Ai, Hanxi Yang, Yuliang Cao
Rok vydání:	2022
Předmět:	General Materials Science
Zdroj:	ACS Applied Materials & Interfaces. 14:43387-43396
ISSN:	1944-8252 1944-8244
Popis:	Sodium metal is a promising anode for high-energy-density sodium rechargeable batteries (RSBs). However, the low Coulombic efficiency (CE) of the Na plating/stripping process and the problem of safety hinder their practical application. Herein, we report a facile strategy for employing the fluorinated phosphate solvents to realize highly reversible Na plating/stripping and improve the safety performance. The fluorinated phosphate molecules reduce the polarity of the solvent and lower the coordination number to Na
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6367577894bbdd4eba359249f7233309 https://doi.org/10.1021/acsami.2c13295 Zobrazit plný text záznamu