Synthesis and Characterization of Reactive Energetic Plasticizers for Poly(glycidyl azide-co-tetramethylene glycol)-Based Polyurethane Binders
| Autor: | Yechen Shen, Younghwan Kwon |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
Azides
Materials science Polyurethanes Biomedical Engineering Plasticizer Bioengineering General Chemistry Condensed Matter Physics Catalysis Cycloaddition Glycols chemistry.chemical_compound chemistry Plasticizers Polymer chemistry Click Chemistry General Materials Science Reactivity (chemistry) Azide Prepolymer Polyurethane |
| Zdroj: | Journal of Nanoscience and Nanotechnology. 21:4110-4115 |
| ISSN: | 1533-4880 |
| DOI: | 10.1166/jnn.2021.19184 |
| Popis: | Two reactive energetic plasticizers, 3-((2,2-dinitropropoxy)methoxy)prop-1-yne and 4-((2,2-dinitropropoxy)methoxy)but-1-yne which can react with an azido-containing poly(glycidyl azide-co-tetramethylene glycol) prepolymer by cupper-free 1,3-dipolor cycloaddition (“Click”) reaction, were synthesized and characterized, in order to investigate their plasticizing performance and catalyst-free 1,3-dipolar cycloaddition reactivity on energetic polyurethane binders. Two reactive energetic plasticizers showed better plasticizing performance than commercial energetic plasticizers. In the reactivity point of view, 3-((2,2-dinitropropoxy)methoxy)prop-1-yne exhibited higher Click reactivity than 4-((2,2-dinitropropoxy)methoxy)but-1-yne. Two synthesized plasticizers were found to fulfill the requirements for use as reactive energetic plasticizers. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|