Metal-Free Aerobic Oxidative Cyanation of Tertiary Amines: Azobis(isobutyronitrile) (AIBN) as a Sole Cyanide Source

Autor:	Chao Zhang, Shi-Chen Zhao, Peng-Yu Liu, Yu-Peng He, Fang Yu, Li Fei
Rok vydání:	2017
Předmět:	Pivalic acid 010405 organic chemistry Chemistry Cyanide Organic Chemistry Oxidative phosphorylation Cyanation 010402 general chemistry 01 natural sciences 0104 chemical sciences chemistry.chemical_compound Metal free Azobis(isobutyronitrile) Organic chemistry Sodium acetate
Zdroj:	The Journal of Organic Chemistry. 82:12786-12790
ISSN:	1520-6904 0022-3263
DOI:	10.1021/acs.joc.7b02021
Popis:	An aerobic oxidative cyanation for the synthesis of α-aminonitriles was reported. The formation of C(sp3)-CN bonds was achieved under a metal-free condition by utilizing azobis(isobutyronitrile) as a sole organic cyanide source with the combination of pivalic acid and sodium acetate as additives.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6312246edb6758edad97e6da450609e3 https://doi.org/10.1021/acs.joc.7b02021 Zobrazit plný text záznamu