Application of a montmorillonite clay modified with iron in photo-Fenton process: comparison with goethite and nZVI
| Autor: | Alberto E. Cassano, María Andrea De León, Guadalupe Beatriz Ortiz de la Plata, Marta Sergio, Juan Bussi, Orlando Mario Alfano |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2015 |
| Předmět: |
inorganic chemicals
Fenton Goethite Photo-Fenton Iron Health Toxicology and Mutagenesis Inorganic chemistry Metal Nanoparticles Nanoparticle Fe-PILC INGENIERÍAS Y TECNOLOGÍAS Water Purification Catalysis Zero valent iron chemistry.chemical_compound Environmental Chemistry Minerals Zerovalent iron Chemistry Ingeniería de Procesos Químicos General Medicine Photochemical Processes Pollution Ingeniería Química Montmorillonite Chemical engineering 2-Chlorophenol visual_art Bentonite visual_art.visual_art_medium 2-chlorophenol Leaching (metallurgy) Oxidation-Reduction Iron Compounds Water Pollutants Chemical Chlorophenols |
| DOI: | 10.1007/s11356-014-2681-6 |
| Popis: | Iron pillared clay (Fe-PILC) was prepared from a montmorillonite and was characterized by scanning electron microscopy and X-ray fluorescence. Fe-PILC catalytic activity was evaluated in photo-Fenton processes applied to the degradation of 2-clorophenol. Different catalyst loads were assayed. The Fe-PILC allowed almost complete degradation of the contaminant. An increase in the contaminant degradation rate was observed, following leaching of iron during catalytic assays, which suggest the existence of a homogeneous photo-Fenton mechanism. The catalytic performance of the Fe-PILC was compared with that for goethite and zero valent iron nanoparticles. Differences were found regarding the achieved degradation levels, the efficiency in oxidant consumption, and the extension of iron leaching. Fil: de León, María A.. Universidad de la República; Uruguay Fil: Sergio, Marta. Universidad de la República; Uruguay Fil: Bussi, Juan. Universidad de la República; Uruguay Fil: Ortiz de la Plata, Guadalupe Beatriz. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina Fil: Cassano, Alberto Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina Fil: Alfano, Orlando Mario. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina |
| Databáze: | OpenAIRE |
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