Stevens rearrangement of thioethers with arynes: a facile access to multi-substituted β-keto thioethers

Autor:	Jian Guo, Lin Zihua, Xu Xiaobo, Yun He, Yuyin Liu
Rok vydání:	2017
Předmět:	Stevens rearrangement 010405 organic chemistry Chemistry Organic Chemistry Organic chemistry lipids (amino acids peptides and proteins) Physical and Theoretical Chemistry 010402 general chemistry 01 natural sciences Biochemistry Aryne 0104 chemical sciences
Zdroj:	Organic & Biomolecular Chemistry. 15:2716-2720
ISSN:	1477-0539 1477-0520
Popis:	An effective method for the synthesis of multi-substituted β-keto thioethers via Stevens rearrangement of simple β-keto thioethers with arynes has been developed. In these reactions, successive C-S/C-H/C-C bonds were formed in one pot under mild and transition-metal free conditions to afford multi-substituted β-keto thioethers in moderate to good yields.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::62ed9142200ca9f45faf729a9d864f77 https://doi.org/10.1039/c7ob00277g Zobrazit plný text záznamu