The Elusive β-Unsubstituted Calix[5]pyrrole Finally Captured

Autor:	Grazia Cafeo, Parisi Mf, David J. Williams, Kohnke Fh, La Torre Gl, Pistone Nascone R
Rok vydání:	2002
Předmět:	chemistry.chemical_compound chemistry Stereochemistry Furan Organic Chemistry medicine Physical and Theoretical Chemistry Beta (finance) Biochemistry Chloride Binding constant Pyrrole medicine.drug
Zdroj:	Organic Letters. 4:2695-2697
ISSN:	1523-7052 1523-7060
Popis:	[reaction: see text] The meso-decamethyl-calix[5]pyrrole 2b was synthesized from the furan-based analogue 1b via the homologation of the furan rings to pyrrole, and its solid-state structure was determined by X-ray crystallography: surprisingly, the binding constant of 2b toward chloride is found to be lower than that of the tetrameric analogue 2a.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::62dd04dec5b99aa32efa32f0c08f68c4 https://doi.org/10.1021/ol0262082 Zobrazit plný text záznamu