Copper Selective Polymeric Extractant Synthesized by Ring-Opening Metathesis Polymerization
| Autor: | Vincent M. Lynch, Bradley J. Holliday, Robert Fimognari, Jonathan L. Sessler, Leander M Cinninger |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
inorganic chemicals
chemistry.chemical_classification 010405 organic chemistry Extraction (chemistry) Polymer ROMP Picolinic acid 010402 general chemistry Metathesis 01 natural sciences 0104 chemical sciences Inorganic Chemistry chemistry.chemical_compound Monomer chemistry Polymerization Polymer chemistry Ring-opening metathesis polymerisation Physical and Theoretical Chemistry |
| Zdroj: | Inorganic Chemistry. 57:392-399 |
| ISSN: | 1520-510X 0020-1669 |
| Popis: | Novel polymers bearing pendant picolinic acid functionalities have been synthesized by ring-opening metathesis polymerization (ROMP) for applications in separations-based purification protocols. These polymers and their corresponding monomer were shown to be selective for Cu2+ over a variety of other divalent metal cations as inferred from pH dependent studies carried out under both liquid-liquid and solid-liquid extraction conditions. The polymer system of this study also showed high selectivity for Cu2+ over Ni2+ in mock protocols that could be relevant to the purification of Cu radioisotopes. Separation factors as high as 290 were achieved for extractions from solutions containing a 100-fold excess of Ni2+ relative to Cu2+. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|