The nature of luminescence of KI and KI-Na crystals at low temperature deformation after natural decrease in the symmetry of the lattice

Autor: K. Shunkeyev, A. Barmina, N. Zhanturina, Zh. Ubaev, L. Myasnikova, D. M. Sergeyev, Sh. Sagimbaeva, Z. Aimaganbetova
Jazyk: angličtina
Rok vydání: 2018
Předmět:
Zdroj: Eurasian Journal of Physics and Functional Materials, Vol 2, Iss 3, Pp 267-273 (2018)
ISSN: 2616-8537
2522-9869
Popis: The X-ray luminescence spectra at low temperature (90K) uniaxial deformation were researched for KI and KI-Na crystals, that were stored for more than 10 years. The following regularities were observed: firstly, the intensities of the intrinsic emission bands at 3.3 eV ( π ) and 4.1 eV ( σ ) become equal in comparison with freshly grown crystals; and secondly, with an increase in the degree of low-temperature uniaxial deformation, a gradual shift of the emission spectra occurs in two directions: the luminescence maximum at 3.3 eV shifts towards short wavelengths, the final position is fixed at 3.9 eV, which practically merges with σ -luminescence; the radiation maximum at 3.0 eV (Ex-radiation) is shifted toward long wavelengths, the final position which is fixed at 2.8 eV. Thus, low temperature uniaxial deformation leads to the separation of the emission spectra at 3,3 eV( π ) → 3,9 eV and 3.0 eV ( Ex ) → 2,8 eV, which are interpreted by the separation of weak → on and weak → strong exciton configurations , respectively
Databáze: OpenAIRE