Easy Removal of Methylparaben and Propylparaben from Aqueous Solution Using Nonionic Micellar System

Autor: Safia Habbal, Boumediene Haddou, Christophe Gourdon, Jean-Paul Canselier
Přispěvatelé: Centre National de la Recherche Scientifique - CNRS (FRANCE), Institut National Polytechnique de Toulouse - INPT (FRANCE), Université Toulouse III - Paul Sabatier - UT3 (FRANCE), Université des Sciences et de la Technologie Mohamed Boudiaf d'Oran - USTO (ALGERIA), Laboratoire Physique-Chimie des Matériaux Catalyse et Environnement - LPCME (Oran, Algérie), Université des sciences et de la Technologie d'Oran Mohamed Boudiaf [Oran] (USTO MB), Laboratoire de Génie Chimique (LGC), Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Institut National Polytechnique (Toulouse) (Toulouse INP), Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS), Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
Jazyk: angličtina
Rok vydání: 2019
Předmět:
Zdroj: Tenside Surfactants Detergents
Tenside Surfactants Detergents, Carl Hanser Verlag 2019, 56 (2), pp.112-118. ⟨10.3139/113.110611⟩
ISSN: 0932-3414
DOI: 10.3139/113.110611⟩
Popis: This study aimed to investigate the simultaneous removal of methylparaben (MePB) and propylparaben (PrPB) from effluents (each one at 16 mg/L) using a nonionic micellar system containing Triton X-114. Response surface methodology (RSM) has been carried out. Extraction results using nonionic surfactant two-phase system were considered as a function of surfactant concentration and temperature variation. Four responses were investigated: MePB and PrPB extraction yield (E), solute (Xs,w) and surfactant (Xsf,w) concentrations in the aqueous phase and the volume fraction of micellar phase (ϕC) at equilibrium. Very high extraction efficiencies (99 % for PrPB and 84 % for MePB) were achieved at optimal conditions. Thereby, the amounts of PrPB and MePB were reduced 80 and 5 times, respectively. The extraction improvement using sodium sulfate was also shown. Finally, the solute stripping from micellar phase by pH change was proved.
Databáze: OpenAIRE