Synthesis of Ca(PF$_6$)$_2$, formed $\textit{via}$ nitrosonium oxidation of calcium

Autor: Keyzer, EN, Matthews, PD, Liu, Z, Bond, AD, Grey, CP, Wright, DS
Přispěvatelé: Keyzer, Evan [0000-0002-0655-2813], Liu, Zigeng [0000-0002-2955-5080], Bond, Andrew [0000-0002-1744-0489], Grey, Clare [0000-0001-5572-192X], Wright, Dominic [0000-0002-9952-3877], Apollo - University of Cambridge Repository
Rok vydání: 2017
DOI: 10.17863/cam.8778
Popis: The development of rechargeable Ca-ion batteries as an alternative to Li systems has been limited by the availability of suitable electrolyte salts. We present the synthesis of complexes of Ca(PF$_6$)$_2$ (a key potential Ca battery electrolyte salt) $\textit{via}$ the treatment of Ca metal with NOPF$_6$, and explore their conversion to species containing PO$_2$F$_2$$^{-}$ under the reaction conditions.
Databáze: OpenAIRE