Undescribed diphenyl ethers betaethrins A-I from a desert plant endophytic strain of the fungus Phoma betae A.B. Frank (Didymellaceae)

Autor: Yue Tan, Yan-Duo Wang, Qi Li, Xiao-Ke Xing, Shu-Bin Niu, Bing-Da Sun, Lin Chen, Rui-Le Pan, Gang Ding
Rok vydání: 2022
Předmět:
Zdroj: Phytochemistry. 201:113264
ISSN: 0031-9422
Popis: Ten diphenyl ethers (DPEs), including nine undescribed analogs named betaethrins A-I, were isolated from the desert plant endophytic fungus Phoma betae A.B. Frank (Didymellaceae). Their structures were determined mainly by NMR, HR-ESI-MS spectral and X-ray diffraction experiments. Betaethrins D-I possessed different fatty acid chains connected with the B-ring, which was the first report in all DPEs. The shielding effect of the B-ring on H-6 (A-ring) in methyl barceloneate, betaethrin A and betaethrins D-F (asterric acid analogs) was first observed and analyzed, which could differentiate the
Databáze: OpenAIRE